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Peter V. Sushko

Physical Sciences
Scientist, Team Lead
Pacific Northwest National Laboratory
PO Box 999
MSIN: K2-01
Richland, WA 99352


Peter Sushko received his BSc and MSc degrees in Physics from St. Petersburg State University, Russia, and his PhD in Physics from the University College London (UCL), UK. After completing his PhD in 2000, he held several research positions at the Department of Physics and Astronomy and the London Centre for Nanotechnology, UCL.

In 2008 he was awarded the Royal Society University Research Fellowship and joined academic staff at UCL; he was promoted to a Reader (Associate Professor with tenure) in 2012. In 2014 he joined PNNL’s Physical Sciences Division as an Associate Division Director with responsibilities for materials science. His research is focused on understanding atomic-scale mechanisms of fundamental processes in complex materials systems and predicting the effects of disorder and defects on materials properties and functions.

Research Interests

  • Discovery and design of new materials with novel structures, functions, and properties.
  • Mechanisms of fundamental processes in complex materials, structure property relationships, mechanisms of defect formation, diffusion, aggregation and inter-conversion.
  • Optical, electronic, and magnetic properties of oxides nano-particles, surfaces, interfaces and heterostructures; mechanisms of photo-induced phenomena.
  • Chemical reactivity of excess-electron centers and electron-rich materials.
  • Computational (ab initio) materials modeling.

Education and Credentials

  • PhD in Physics, University College London, UK (2000).
  • MSc in the Quantum Theory of the Solid State, St. Petersburg State University, Russia (1996).
  • BSc in Physics, St. Petersburg State University, Russia (1994).

Affiliations and Professional Service

  • American Chemical Society - member
  • American Physical Society - member
  • Institute of Physics - member

Awards and Recognitions

  • Daiwa Adrian Prize 2013.
  • Royal Society University Research Fellowship (2008-2013 and 2013-2016).
  • Carey Foster Prize for the best postgraduate research in physics, Department of Physics and Astronomy, University College London (2000).
  • Overseas Research Students Award, the Committee of Vice-Chancellors and Principals of the Universities of the UK (1997-1999).
  • Mayor of St. Petersburg award for undergraduate students (1994 and 1995).
  • International Soros Science Program Award (1994).

PNNL Publications


  • Spurgeon SR, P Sushko, A Devaraj, Y Du, TC Droubay, and SA Chambers. 2018. "Onset of Phase Separation in the Double Perovskite Oxide La2MnNiO6." Physical Review B 97(13):134110.  doi:10.1103/PhysRevB.97.134110


  • Nayyar IH, SE Chamberlin, TC Kaspar, N Govind, SA Chambers, and P Sushko. 2017. "Effect of doping and chemical ordering on the optoelectronic properties of complex oxides: Fe2O3-V2O3 solid solutions and hetero-structures." Physical Chemistry Chemical Physics. PCCP 19(2):1097-1107.  doi:10.1039/C6CP06087K
  • Ong PV, Y Du, and P Sushko. 2017. "Low Dimensional Oxygen Vacancy Ordering and Diusion in SrCrO3-d." Journal of Physical Chemistry Letters 8(8):1757-1763.  doi:10.1021/acs.jpclett.7b00355
  • Spurgeon SR, P Sushko, SA Chambers, and RB Comes. 2017. "Dynamic Interface Rearrangement in LaFeO3 / n-SrTiO3 Heterojunctions." Physical Review Materials 1(6):063401.  doi:10.1103/PhysRevMaterials.1.063401
  • Chambers SA, TC Droubay, TC Kaspar, IH Nayyar, ME McBriarty, SM Heald, DJ Keavney, ME Bowden, and P Sushko. 2017. "Electronic and Optical Properties of a Semiconducting Spinel (Fe2CrO4)." Advanced Functional Materials 27(9):Article No. 1605040.  doi:10.1002/adfm.201605040
  • Chambers SA, Y Du, RB Comes, SR Spurgeon, and P Sushko. 2017. "The effects of core-level broadening in determining band alignment at the epitaxial SrTiO3(001)/p-Ge(001) heterojunction." Applied Physics Letters 110(8):082104.  doi:10.1063/1.4977422
  • Comes RB, SR Spurgeon, DM Kepaptsoglou, MH Engelhard, DE Perea, TC Kaspar, QM Ramasse, P Sushko, and SA Chambers. 2017. "Probing the Origin of Interfacial Carriers in SrTiO3-LaCrO3 Superlattices." Chemistry of Materials 29(3):1147-1155.  doi:10.1021/acs.chemmater.6b04329
  • Moghadam R, ZY Xiao, K Ahmadi-Majlan, E Grimley, ME Bowden, PV Ong, SA Chambers, JM LeBeau, X Hong, P Sushko, and J Ngai. 2017. "An Ultrathin Single Crystalline Relaxor Ferroelectric Integrated on a High Mobility Semiconductor." Nano Letters 17(10):6248-6257.  doi:10.1021/acs.nanolett.7b02947
  • Ong PV, LEV Johnson, H Hosono, and P Sushko. 2017. "Structure and stability of CaH2 surfaces: on the possibility of electron-rich surfaces in metal hydrides for catalysis." Journal of Materials Chemistry A 5(11):5550-5558.  doi:10.1039/C6TA09561E
  • Zhu Y, P Sushko, D Melzer, E Jensen, L Kovarik, C Ophus, M Sanchez-Sanchez, JA Lercher, and ND Browning. 2017. "Formation of Oxygen Radical Sites on MoVNbTeOx by Cooperative Electron Redistribution." Journal of the American Chemical Society 139(36):12342-12345.  doi:10.1021/jacs.7b05240


  • Johnson LEV, P Sushko, Y Tomota, and H Hosono. 2016. "Electron anions and the glass transition temperature." Proceedings of the National Academy of Sciences of the United States of America 113(36):10001-10012.  doi:10.1073/pnas.1606891113
  • Kaspar TC, P Sushko, ME Bowden, SM Heald, A Papadogianni, CM Tschammer, O Bierwagen, and SA Chambers. 2016. "Defect compensation by Cr vacancies and oxygen interstitials in Ti4+-doped Cr2O3 epitaxial thin films." Physical Review. B, Condensed Matter and Materials Physics 94(15):Article No. 155409.  doi:10.1103/PhysRevB.94.155409
  • Comes RB, SR Spurgeon, SM Heald, DM Kepaptsoglou, L Jones, PV Ong, ME Bowden, QM Ramasse, P Sushko, and SA Chambers. 2016. "Interface-Induced Polarization in SrTiO3-LaCrO3 Superlattices ." Advanced Materials Interfaces 3(6):Art. No. 1500779.  doi:10.1002/admi.201500779
  • Dicks OA, AL Shluger, P Sushko, and P Littlewood. 2016. "Spectroscopic properties of oxygen vacancies in LaAlO3." Physical Review. B, Condensed Matter 93(13):Article No. 134114.  doi:10.1103/PhysRevB.93.134114
  • Konstantinou K, P Sushko, and DM Duffy. 2016. "Modelling the local atomic structure of molybdenum in nuclear waste glasses with ab initio molecular dynamics simulations." Physical Chemistry Chemical Physics. PCCP 18(37):26125-26132.  doi:10.1039/C6CP03076A
  • Spurgeon SR, Y Du, TC Droubay, A Devaraj, X Sang, P Longo, P Yan, PG Kotula, V Shutthanandan, ME Bowden, JM LeBeau, CM Wang, P Sushko, and SA Chambers. 2016. "Competing Pathways for Nucleation of the Double Perovskite Structure in the Epitaxial Synthesis of La2MnNiO6." Chemistry of Materials 28(11):3814-3822.  doi:10.1021/acs.chemmater.6b00829
  • Xu P, TC Droubay, JS Jeong, KA Mkhoyan, P Sushko, SA Chambers, and B Jalan. 2016. "Quasi 2D Ultrahigh Carrier Density in a Complex Oxide Broken Gap Heterojunction." Advanced Materials Interfaces 3(2):Article No. 1500432.  doi:10.1002/admi.201500432
  • Xu P, Y Ayino, CJ Cheng, VS Pribiag, RB Comes, P Sushko, SA Chambers, and B Jalan. 2016. "Predictive Control over Charge Density in the Two-Dimensional Electron Gas at the Polar-Nonpolar NdTiO3/SrTiO3 Interface." Physical Review Letters 117(10):106806-6.  doi:10.1103/PhysRevLett.117.106803


  • Zhang H, Y Du, A Papadogianni, O Bierwagen, S Sallis, LFJ Piper, ME Bowden, V Shutthanandan, P Sushko, and SA Chambers. 2015. "Perovskite Sr-doped LaCrO3 as a new p-type transparent conducting oxide." Advanced Materials 27(35):5191-5195.  doi:10.1002/adma.201501959
  • Zhang H, Y Du, P Sushko, ME Bowden, V Shutthanandan, L Qiao, G Cao, Z Gai, S Sallis, LFJ Piper, and SA Chambers. 2015. "Electronic and magnetic properties of epitaxial perovskite SrCrO3(001)." Journal of Physics: Condensed Matter 27(24):245605.  doi:10.1088/0953-8984/27/24/245605
  • Zhang H, Y Du, P Sushko, ME Bowden, V Shutthanandan, S Sallis, LFJ Piper, and SA Chambers. 2015. "Hole-induced insulator-to-metal transition in La1-xSrxCrO3 epitaxial films." Physical Review. B, Condensed Matter and Materials Physics 91(15):155129.  doi:10.1103/PhysRevB.91.155129
  • Chamberlin SE, IH Nayyar, TC Kaspar, P Sushko, and SA Chambers. 2015. "Electronic structure and optical properties of a-(Fe1-xVx)2O3 solid-solution thin films." Applied Physics Letters 106(4):041905.  doi:10.1063/1.4906597
  • Chambers SA, Y Du, M Gu, TC Droubay, S Hepplestone, and P Sushko. 2015. "Dominance of interface chemistry over the bulk properties in determining the electronic structure of epitaxial metal/perovskite oxide heterojunctions." Chemistry of Materials 27(11):4093-4098.  doi:10.1021/acs.chemmater.5b01118
  • Cheng Y, Y Shao, LR Parent, ML Sushko, G Li, P Sushko, ND Browning, CM Wang, and J Liu. 2015. "Interface Promoted Reversible Mg Insertion in Nanostructured Tin-Antimony Alloys." Advanced Materials 27(42):6598-6605.  doi:10.1002/adma.201502378
  • Kimmel AV, and P Sushko. 2015. "Mechanisms of formation of chemical bonds and defect formation at the a-SiO2/BaTiO3 interfaces." Journal of Physics: Condensed Matter 27(47):Article No. 475006.  doi:10.1088/0953-8984/27/47/475006
  • Kitano M, S Kanbara, Y Inoue, N Kuganathan, P Sushko, T Yokoyama, M Hara, and H Hosono. 2015. "Electride support boosts nitrogen dissociation over ruthenium catalyst and shifts the bottleneck in ammonia synthesis." Nature Communications 6:Article No. 6731.  doi:10.1038/ncomms7731
  • Konstantinou K, P Sushko, and DM Duffy. 2015. "Structure and ionic diffusion of alkaline-earth ions in mixed cation glasses ." Journal of Non-crystalline Solids 422:57-63.  doi:10.1016/j.jnoncrysol.2015.05.005
  • Parent LR, Y Cheng, P Sushko, Y Shao, J Liu, CM Wang, and ND Browning. 2015. "Realizing the Full Potential of Insertion Anodes for Mg-ion Batteries Through the Nano-Structuring of Sn." Nano Letters 15(2):1177-1182.  doi:10.1021/nl5042534


  • Comes RB, P Sushko, SM Heald, RJ Colby, ME Bowden, and SA Chambers. 2014. "Band-Gap Reduction and Dopant Interaction in Epitaxial La,Cr Co-doped SrTiO3 Thin Films." Chemistry of Materials 26(24):7073-7082.  doi:10.1021/cm503541u
  • Kaspar TC, SE Chamberlin, ME Bowden, RJ Colby, V Shutthanandan, S Manandhar, Y Wang, P Sushko, and SA Chambers. 2014. "Impact of Lattice Mismatch and Stoichiometry on the Structure and Bandgap of (Fe,Cr)2O3 Epitaxial Thin Films." Journal of Physics: Condensed Matter 26(13):Article No. 135005.  doi:10.1088/0953-8984/26/13/135005
  • Zhang H, P Sushko, RJ Colby, Y Du, ME Bowden, and SA Chambers. 2014. "Reversible nano-structuring of SrCrO3-d through oxidization and reduction at low temperatures." Nature Communications 5:Artcle No. 4669.  doi:10.1038/ncomms5669


  • Chambers SA, M Gu, PV Sushko, H Yang, CM Wang, and ND Browning. 2013. "Ultra-low contact resistance at an epitaxial metal/oxide heterojunction through interstitial site doping." Advanced Materials 25(29):4001-4005.  doi:10.1002/adma.201301030
  • Sushko PV, KM Rosso, J Zhang, J Liu, and ML Sushko. 2013. "Oxygen vacancies and ordering of d-levels control voltage suppression in oxide cathodes: the case of spinel LiNi0.5Mn1.5O4-d ." Advanced Functional Materials 23(44):5530-5535.  doi:10.1002/adfm.201301205
  • Wang Y, KA Lopata, SA Chambers, N Govind, and PV Sushko. 2013. "Optical absorption and band gap reduction in (Fe1-xCrx)2O3 solid solutions: A first-principles study." Journal of Physical Chemistry C 117(48):25504-25512.  doi:10.1021/jp407496w


  • McLeod JA, A Buling, EZ Kurmaev, PV Sushko, N Neumann, LD Finkelstein, SW Kim, H Hosono, and A Moewes. 2012. "Spectroscopic Characterization of a Multiband Complex Oxide: Insulating and Conducting Cement 12CaO·7Al2O3." Physical Review. B, Condensed Matter and Materials Physics 85(4):045204 - 045212.  doi:10.1103/PhysRevB.85.045204
  • McLeod JA, EZ Kurmaev, PV Sushko, TD Boyko, IA Levitsky, and A Moewes. 2012. "Selective Response of Mesoporous Silicon to Adsorbants with Nitro Groups." Chemistry - A European Journal 18(10):2912-2922.  doi:10.1002/chem.201102084


  • Sushko PV, AL Shluger, AG Joly, KM Beck, and WP Hess. 2011. "Exciton-driven highly hyperthermal O-atom desorption from nanostructured CaO." Journal of Physical Chemistry C 115(3):692-699.  doi:10.1021/jp1078423
  • Mckenna KP, D Koller, A Sternig, N Siedl, N Govind, PV Sushko, and OE Diwald. 2011. "Optical Properties of Nanocrystal Interfaces in Compressed MgO Nanopowders." ACS Nano 5(4):3003-3009.  doi:10.1021/nn200062d


  • Sushko ML, PV Sushko, IV Abarenkov, and AL Shluger. 2010. "QM/MM method for metal - organic interfaces." Journal of Computational Chemistry 31(16):2955-2966.  doi:10.1002/jcc.21591
  • Sushko PV, KP Mckenna, D Munoz Ramo, AL Shlyuger, A Sternig, S Stankic, M Muller, and OE Diwald. 2010. "Photoluminescence Properties of Alkaline-Earth Oxide Nanoparticles." ECS Transactions 28(3):67-80.  doi:10.1149/1.3367212
  • Sushko PV, KM Rosso, and IV Abarenkov. 2010. "Interaction of Intercalated Li+ Ions with Oxygen Vacancies in Rutile TiO2." ECS Transactions 28(11):299-306. 


  • Govind N, PV Sushko, WP Hess, M Valiev, and K Kowalski. 2009. "Excitons in Potassium Bromide: A Study using Embedded Time-dependent Density Functional Theory and Equation-of-Motion Coupled Cluster Methods." Chemical Physics Letters 470(4-6):353-357.  doi:10.1016/j.cplett.2009.01.073
  • Shluger AL, KP Mckenna, PV Sushko, DM Ramo, and AV Kimmel. 2009. "Modelling of electron and hole trapping in oxides." Modelling and Simulation in Materials Science and Engineering 17(8):084004 (23 pages).  doi:10.1088/0965-0393/17/8/084004
  • Trevisanutto PE, PV Sushko, KM Beck, AG Joly, WP Hess, and AL Shluger. 2009. "Excitation, Ionization, and Desorption: How Sub-band gap Photons Modify the Structure of Oxide Nanoparticles." Journal of Physical Chemistry C 113(4):1274-1279. 


  • Beck KM, AG Joly, OE Diwald, S Stankic, PE Trevisanutto, PV Sushko, AL Shluger, and WP Hess. 2008. "Energy and Site Selectivity in O-Atom Photodesorption from Nanostructured MgO." Surface Science 602(11):1968-1973.  doi:10.1016/j.susc.2008.03.046


  • Joly AG, M Henyk, KM Beck, PE Trevisanutto, PV Sushko, WP Hess, and AL Shluger. 2006. "Probing Electron Transfer Dynamics at MgO Surfaces by Mg-Atom Desorption." Journal of Physical Chemistry B 110(37):18093-18096.  doi:10.1021/jp064092b


  • Hess WP, AG Joly, KM Beck, M Henyk, PV Sushko, PE Trevisanutto, and AL Shluger. 2005. "Laser Control of Desorption Through Selective Surface Excitation." Journal of Physical Chemistry B 109(42):19563-19578.  doi:10.1021/jp0523672
  • Trevisanutto PE, PV Sushko, AL Shluger, KM Beck, M Henyk, AG Joly, and WP Hess. 2005. "A Mechanism of Photo-Induced Desorption of Oxygen Atoms From MgO Nano-Crystals." Surface Science 593(1-3):210-220. 


  • Hess WP, AG Joly, KM Beck, PV Sushko, and AL Shluger. 2004. "Determination of Surface Exciton Energies by Velocity Resolved Atomic Desorption." Surface Science 564(1-3):62-70. 


  • Joly AG, KM Beck, M Henyk, WP Hess, PV Sushko, and AL Shluger. 2003. "Surface Electronic Spectra Detected by Atomic Desorption." Surface Science 544(1):L683-L688. 


  • Hess WP, AG Joly, DP Gerrity, KM Beck, PV Sushko, and AL Shluger. 2002. "Control of Laser Desorption Using Tunable Single Pulses and Pulse Pairs." Journal of Chemical Physics 116(18):8144-8151. 
  • Hess WP, AG Joly, KM Beck, DP Gerrity, PV Sushko, and AL Shluger. 2002. "Solid-State Halogen Atom Source for Chemical Dynamics and Etching." Applied Physics Letters 81(6):1140-1142. 

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