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Nikolay

Nikolay Petrik

Chemical Physics & Analysis
Chemist
Pacific Northwest National Laboratory
PO Box 999
MSIN: K8-88
Richland, WA 99352

Biography

Dr. Nikolay Petrik's main expertise is in field of radiation-induced processes at surfaces and interfaces induced by photons, electrons, gamma rays and other sources of radiation. These studies include primary events, migration of electronic excitation, and desorption of molecular and atomic products. Before joining Pacific Northwest National Laboratory in 1997, Dr. Petrik worked as a senior scientist at the All-Russian Research Institute of Complex Power Technology (VNIPIET) in St. Petersburg, Russia.

Research Interests

  • Thermal and non-thermal (photo-, electron-) chemistry of various molecules (O2, H2O, CO, CO2, TMAA, Ar, Kr, Xe, and others) on the surface of oxides (TiO2, ZrO2, and others) and metals (Pt, Pd, Zr and others)
  • Radiation-induced processes in water and organic nano-films induced by low energy electrons
  • Structure and hydrogen bonding of small molecules on metal and oxide surfaces (e.g., TiO2(110), Pt(111), and others)
  • Electron- and photon-simulated luminescence in condense matter and heterogeneous systems
  • Photoionization of liquid nano-jets

Education and Credentials

  • Doctor of Sciences in Chemistry, Institute of Technology, St. Petersburg, Russia
  • Ph.D. in Chemistry, Institute of Technology, St. Petersburg, Russia
  • M.S. (with distinction), Chemical Technology, Physical and Radiation Chemistry, Institute of Technology, St. Petersburg, Russia

Affiliations and Professional Service

  • American Chemical Society
  • American Vacuum Society

PNNL Publications

2017

  • Mu R., A.P. Dahal, Z. Wang, Z. Dohnalek, G.A. Kimmel, N.G. Petrik, and I.V. Lyubinetsky. 2017. "Adsorption and Photodesorption of CO from Charged Point-Defects on TiO2(110)." Journal of Physical Chemistry Letters 8, no. 18:4565-4572. PNNL-SA-128233. doi:10.1021/acs.jpclett.7b02052

2016

  • Petrik N.G., G.A. Kimmel, M. Shen, and M.A. Henderson. 2016. "Quenching of Electron Transfer Reactions through Coadsorption: A Study of Oxygen Photodesorption from TiO2(110)." Surface Science 652. PNNL-SA-114433. doi:10.1016/j.susc.2015.12.038
  • Xu Y., C.J. Dibble, N.G. Petrik, R.S. Smith, A.G. Joly, R.G. Tonkyn, and B.D. Kay, et al. 2016. "A nanosecond pulsed laser heating system for studying liquid and supercooled liquid films in ultrahigh vacuum." Journal of Chemical Physics 144, no. 16:Article No. 164201. PNNL-SA-115728. doi:10.1063/1.4947304
  • Xu Y., C.J. Dibble, N.G. Petrik, R.S. Smith, B.D. Kay, and G.A. Kimmel. 2016. "Complete wetting of Pt(111) by nanoscale liquid water films." Journal of Physical Chemistry Letters 7, no. 3:541-547. PNNL-SA-114918. doi:10.1021/acs.jpclett.5b02748

2015

  • Petrik N.G., and G.A. Kimmel. 2015. "Reaction Kinetics of Water Molecules with Oxygen Vacancies on Rutile TiO2(110)." Journal of Physical Chemistry C 119, no. 40:23059-23067. PNNL-SA-111828. doi:10.1021/acs.jpcc.5b07526
  • Petrik N.G., M.A. Henderson, and G.A. Kimmel. 2015. "Insights into Acetone Photochemistry on Rutile TiO2(110). 1. Off-Normal CH3 Ejection from Acetone Diolate." Journal of Physical Chemistry C 119, no. 22:12262-12272. PNNL-SA-108620. doi:10.1021/acs.jpcc.5b02477
  • Petrik N.G., M.A. Henderson, and G.A. Kimmel. 2015. "Insights into Acetone Photochemistry on Rutile TiO2(110). 2. New Photodesorption Channel with CH3 Ejection along the Surface Normal." Journal of Physical Chemistry C 119, no. 22:12273-12282. PNNL-SA-108621. doi:10.1021/acs.jpcc.5b02478
  • Yoon Y., Y. Du, J.C. Garcia, Z. Zhu, Z. Wang, N.G. Petrik, and G.A. Kimmel, et al. 2015. "Anticorrelation between Surface and Subsurface Point Defects and the Impact on the Redox Chemistry of TiO2(110)." ChemPhysChem 16, no. 2:313-321. PNNL-SA-105906. doi:10.1002/cphc.201402599

2014

  • Kimmel G.A., T. Zubkov, R.S. Smith, N.G. Petrik, and B.D. Kay. 2014. "Turning things downside up: Adsorbate induced water flipping on Pt(111)." Journal of Chemical Physics 141, no. 18:18C515. PNNL-SA-103931. doi:10.1063/1.4896226
  • Petrik N.G., and G.A. Kimmel. 2014. "Probing the photochemistry of chemisorbed oxygen on TiO2(110) with Kr and other co-adsorbates." Physical Chemistry Chemical Physics. PCCP 16, no. 6:2338-2346. PNNL-SA-98647. doi:10.1039/c3cp54195a
  • Petrik N.G., R.J. Monckton, S. Koehler, and G.A. Kimmel. 2014. "Distance-dependent radiation chemistry: Oxidation versus hydrogenation of CO in electron-irradiated H2O/CO/H2O ices." Journal of Physical Chemistry C 118, no. 47:27483-27492. PNNL-SA-105600. doi:10.1021/jp509785d
  • Petrik N.G., R.J. Monckton, S. Koehler, and G.A. Kimmel. 2014. "Electron-stimulated reactions in layered CO/H2O films: Hydrogen atom diffusion and the sequential hydrogenation of CO to methanol." Journal of Chemical Physics 140, no. 20:Article No. 204710. PNNL-SA-100690. doi:10.1063/1.4878658

2013

  • Petrik N.G., and G.A. Kimmel. 2013. "Multiple Non-Thermal Reaction Steps for the Photooxidation CO to CO2 on Reduced TiO2(110)." The Journal of Physical Chemistry Letters 4, no. 3:344-349. PNNL-SA-92421. doi:10.1021/jz302012j

2012

  • Du Y., N.G. Petrik, N.A. Deskins, Z. Wang, M.A. Henderson, G.A. Kimmel, and I. Lyubinetsky. 2012. "Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces Prepared via Carboxylic Acid Adsorption and Photolysis." Physical Chemistry Chemical Physics. PCCP 14, no. 9:3066-3074. PNNL-SA-82616. doi:10.1039/C1CP22515D
  • Kimmel G.A., M.D. Baer, N.G. Petrik, J. VandeVondele, R.J. Rousseau, and C.J. Mundy. 2012. "Polarization- and Azimuth-Resolved Infrared Spectroscopy of Water on TiO2(110): Anisotropy and the Hydrogen-Bonding Network." The Journal of Physical Chemistry Letters 3, no. 6:778-784. PNNL-SA-85286. doi:10.1021/jz3001079
  • Lin X., Y. Yoon, N.G. Petrik, Z. Li, Z. Wang, V.A. Glezakou, and B.D. Kay, et al. 2012. "Structure and Dynamics of CO2 on Rutile TiO2(110)-1x1." Journal of Physical Chemistry C 116, no. 50:26322-26334. PNNL-SA-89052. doi:10.1021/jp308061j
  • Petrik N.G., and G.A. Kimmel. 2012. "Adsorption geometry of CO versus coverage on TiO2(110) from s- and p-polarized infrared spectroscopy." Journal of Physical Chemistry Letters 3, no. 23:3425-3430. PNNL-SA-90608. doi:10.1021/jz301413v
  • Smith R.S., N.G. Petrik, G.A. Kimmel, and B.D. Kay. 2012. "Thermal and Non-thermal Physiochemical Processes in Nanoscale Films of Amorphous Solid Water." Accounts of Chemical Research 45, no. 1:33-42. PNNL-SA-78512. doi:10.1021/ar200070w

2011

  • Feibelman P.J., G.A. Kimmel, R.S. Smith, N.G. Petrik, T. Zubkov, and B.D. Kay. 2011. "A unique vibrational signature of rotated water monolayers on Pt(111): predicted and observed." Journal of Chemical Physics 134, no. 20:Article No. 204702. PNNL-SA-77579. doi:10.1063/1.3591966
  • Petrik N.G., and G.A. Kimmel. 2011. "Electron- and hole-mediated reactions in UV -irradiated O2 adsorbed on reduced rutile TiO2(110)." Journal of Physical Chemistry C 115, no. 1:152-164. PNNL-SA-71556. doi:10.1021/jp108909p
  • Petrik N.G., and G.A. Kimmel. 2011. "Oxygen Photochemistry on TiO2(110): Recyclable, Photoactive Oxygen Produced by Annealing Adsorbed O2." The Journal of Physical Chemistry Letters 2, no. 21:2790-2796. PNNL-SA-82849. doi:10.1021/jz201225c

2010

  • Petrik N.G., and G.A. Kimmel. 2010. "Off-normal CO2 desorption from the photooxidation of CO on reduced TiO2(110)." The Journal of Physical Chemistry Letters 1, no. 17:2508-2513. PNNL-SA-73722. doi:10.1021/jz100884w
  • Petrik N.G., and G.A. Kimmel. 2010. "Photoinduced Dissociation of O2 on Rutile TiO2(110)." The Journal of Physical Chemistry Letters 1, no. 12:1758-1762. PNNL-SA-72411. doi:10.1021/jz100513e

2009

  • Akin M.C., N.G. Petrik, and G.A. Kimmel. 2009. "Electron-Stimulated Reactions and O-2 Production in Methanol-Covered Amorphous Solid Water Films." Journal of Chemical Physics 130, no. 10:Art. No. 104710. PNNL-SA-62554.
  • Kimmel G.A., J. Matthiesen, M. Baer, C.J. Mundy, N.G. Petrik, R.S. Smith, and Z. Dohnalek, et al. 2009. "No Confinement Needed: Observation of a Metastable Hydrophobic Wetting Two-Layer Ice on Graphene." Journal of the American Chemical Society 131, no. 35:12838-12844. PNNL-SA-65864.
  • Petrik N.G., and G.A. Kimmel. 2009. "Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated Production of H-2 and O-2 in Amorphous Solid Water Films on TiO2(110)." Journal of Physical Chemistry C 113, no. 11:4451-4460. PNNL-SA-60869.
  • Petrik N.G., Z. Zhang, Y. Du, Z. Dohnalek, I. Lyubinetsky, and G.A. Kimmel. 2009. "Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption." Journal of Physical Chemistry C 113, no. 28:12407-12411. PNNL-SA-65119. doi:10.1021/jp901989x
  • Zhang Z., Y. Du, N.G. Petrik, G.A. Kimmel, I. Lyubinetsky, and Z. Dohnalek. 2009. "Water as a Catalyst: Imaging Reactions of O-2 with Partially and Fully Hydroxylated TiO2(110) Surfaces." Journal of Physical Chemistry C 113, no. 5:1908-1916. PNNL-SA-62836.

2008

  • Grieves G.A., N.G. Petrik, J. Herring-Captain, B. Olanrewaju, A. Aleksandrov, R.G. Tonkyn, and S.E. Barlow, et al. 2008. "Photoionization of Sodium Salt Solutions in a Liquid Jet." Journal of Physical Chemistry C 112, no. 22:8359-8364. PNNL-SA-58466. doi:10.1021/jp7102534
  • Kimmel G.A., and N.G. Petrik. 2008. "Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies." Physical Review Letters 100, no. 19:Art. No. 196102. PNNL-SA-58431. doi:10.1103/PhysRevLett.100.196102

2007

  • Kimmel G.A., N.G. Petrik, Z. Dohnalek, and B.D. Kay. 2007. "Crystalline Ice Growth on Pt(111) and Pd(111): Nonwetting Growth on a Hydrophobic Water Monolayer." Journal of Chemical Physics 126, no. 11:Art. No. 114702. PNNL-SA-51889.
  • Lane C.D., N.G. Petrik, T.M. Orlando, and G.A. Kimmel. 2007. "Electron-Stimulated Oxidation of Thin Water Films Adsorbed on TiO2(110)." Journal of Physical Chemistry C 111, no. 44:16319-16329. PNNL-SA-54544. doi:10.1021/jp072479o
  • Lane C.D., N.G. Petrik, T.M. Orlando, and G.A. Kimmel. 2007. "Site-Dependent Electron-Stimulated Reactions in Water Films on TiO2(110)." Journal of Chemical Physics 127, no. 22:Art. No. 224706. PNNL-SA-56026.
  • Petrik N.G., and G.A. Kimmel. 2007. "Hydrogen Bonding, H-D Exchange, and Molecular Mobility in Thin Water Films on TiO2(110)." Physical Review Letters 99, no. 19:Art.No.196103. PNNL-SA-55179. doi:10.1103/PhysRevLett.99.196103

2006

  • Kimmel G.A., N.G. Petrik, Z. Dohnalek, and B.D. Kay. 2006. "Layer-by-Layer Growth of Thin Amorphous Solid Water Films on Pt(111) and Pd(111)." Journal of Chemical Physics 125, no. 4:044713-1 - 044713-12. PNNL-SA-48867. doi:10.1063/1.2218844
  • Petrik N.G., A.G. Kavetski, and G.A. Kimmel. 2006. "Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water on Pt(111): Precursor Transport Through the Hydrogen Bonding Network." Journal of Chemical Physics 125, no. 12:124702 (11 p.). PNNL-SA-50526.
  • Petrik N.G., A.G. Kavetski, and G.A. Kimmel. 2006. "Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water." Journal of Physical Chemistry B 110, no. 6:2723-2731. PNNL-SA-46633.

2005

  • Garrett B.C., D.A. Dixon, D.M. Camaioni, D.M. Chipman, M.A. Johnson, C.D. Jonah, and G.A. Kimmel, et al. 2005. "Role of Water in Electron-Initiated Processes and Radical Chemistry: Issues and Scientific Advances." Chemical Reviews 105, no. 1:355-389. PNNL-SA-42304. doi:10.1021/cr030453x
  • Kimmel G.A., N.G. Petrik, Z. Dohnalek, and B.D. Kay. 2005. "Crystalline Ice Growth on Pt(111): Observation of a Hydrophobic Water Monolayer." Physical Review Letters 95, no. 16:166102. PNNL-SA-45342.
  • Petrik N.G., and G.A. Kimmel. 2005. "Electron-Stimulated Sputtering of Thin Amorphous Solid Water Films on Pt(111)." Journal of Chemical Physics 123, no. 5:054702 (1-7). PNNL-SA-42923.
  • Petrik N.G., and G.A. Kimmel. 2005. "Low-Energy Electron-Stimulated Luminescence of Thin H20 and D20 Layers on Pt(111)." Journal of Physical Chemistry B 109, no. 33:15835-15841. PNNL-SA-43848.

2004

  • Petrik N.G., and G.A. Kimmel. 2004. "Electron-Stimulated Production of Molecular Hydrogen at the Interfaces of Amorphous Solid Water Films on Pt(111)." Journal of Chemical Physics 121, no. 8:3736-3744. PNNL-SA-41294.
  • Petrik N.G., and G.A. Kimmel. 2004. "Electron-Stimulated Reactions in Thin D2O Films on Pt(111) Mediated by Electron Trapping." Journal of Chemical Physics 121, no. 8:3727-3735. PNNL-SA-41765.

2003

  • Petrik N.G., and G.A. Kimmel. 2003. ""Electron-Simulated Reactions at the Interfaces of Amorphous Solid Water Films Driven by Long-Range Energy Transfer from the Bulk"." Physical Review Letters 90, no. 16:166102. PNNL-SA-37444.

2001

  • Mccord T.B., T.M. Orlando, G.R. Teeter, G.B. Hansen, M.T. Sieger, N.G. Petrik, and L.M. Van Keulen. 2001. "Thermal and Radiation Stability of the Hydrated Salt Minerals Epsomite, Mirabilite and Natron Under Europa Environmental Conditions." Journal of Geophysical Research. Planets 106, no. E2:3311-3319. PNNL-SA-33290.
  • Petrik N.G., A.B. Alexandrov, and A.I. Vall. 2001. "Interfacial Energy Transfer during Gamma Radiolysis of Water on the Surface of ZrO2 and Some Other Oxides." Journal of Physical Chemistry B 105, no. 25:5935-5944. PNNL-SA-33910.

2000

  • Petrik N.G., K. Knutsen, E. Paparazzo, A.S. Lea, D.M. Camaioni, and T.M. Orlando. 2000. "Electron Beam Induced Damage of NaNO3 Single Crystals: An Energy, Temperature, and Quantum State Resolved Study." Journal of Physical Chemistry B 104, no. 7:1563-1571. PNNL-SA-32130.

1999

  • Petrik N.G., D.P. Taylor, and T.M. Orlando. 1999. "Laser-Stimulated Luminescence of Yttria-Stabilized Cubic Zirconia Crystals." Journal of Applied Physics 85, no. 9:6770-6776. PNNL-SA-30599.

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