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February 2019

Organic Particles Modulate Soot Mixing in the Atmosphere

New research shows how the viscosity of organic particles affects the mixing state of soot and alters its warming or cooling potential.

sacramento, california, skyline in haze
The 2010 Carbonaceous Aerosol and Radiative Effects Study (CARES) explored the evolution of atmospheric particles, or aerosols, as they traveled through a rural/urban air transport region in central California. Haze that obscured the Sacramento skyline provided more aerosols for researchers to study. Image courtesy of the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility.

The Science

In the atmosphere, individual soot particles emitted from human activities often encounter and combine with organic material, forming soot-containing particles. A research team led by scientists from the U.S. Department of Energy's (DOE) Pacific Northwest National Laboratory and Michigan Technological University established a link between the viscosity of the organic material and its distribution within the soot-containing particle. This mixing configuration is important because it alters the particles' ability to absorb and scatter solar radiation.

The scientists discovered that organic material of low viscosity partially or completely encapsulated soot particles, while highly viscous organic material often attaches to the surface of co-existing soot particles or do not even stick together, remaining separate.

The Impact

Soot particles strongly absorb solar radiation, and therefore, affect Earth's energy balance. However, their optical properties strongly depend on how the individual soot particles mix with other particles in the atmosphere (internal mixing).

This study identified the viscosity of organic matter in the atmosphere as a key factor that influences the distribution of organic matter within soot-containing particles. These findings will improve aerosol models that predict the mixing state of soot via condensation and coagulation processes, thereby improving radiative forcing calculations and climate predictions.

Summary

Organic particles in the atmosphere exhibit a wide range of viscosity, depending upon their chemical composition and the surrounding environmental conditions, such as temperature and relative humidity. As soot particles combine with organic particles in the atmosphere, the distribution of soot and organic material in the combined particle determines its overall optical properties and radiative forcing-warming or cooling effects.

Taking scanning electron microscopy images at different view angles, researchers investigated soot-containing particles collected during DOE's Carbonaceous Aerosol and Radiative Effects Study (CARES) in Sacramento, California, in June 2010. Their results indicate that organic material of low to intermediate viscosity often engulfed soot, while highly viscous organic material attaches to the soot surface or remains separated from it. Soot particles engulfed by low viscosity organics become coated and can be approximately represented by a "core-shell" model, where the soot particles are at the center of an idealized spherical shell made of the organic material. In contrast, increasing viscosity results in limited (partial) engulfing, and hence the formation of non-core-shell configurations.

These findings establish a link between the viscosity of organic material and its distribution when mixed internally with soot particles. Accounting for the effects of viscosity of organic matter on the mixing state of soot-containing particles in numerical models will improve estimates of radiative forcing from soot.

Acknowledgments

Sponsors: This research was funded by the U.S. Department of Energy Atmospheric System Research (ASR) Program under Contract DE-SC0010019 at Michigan Technological University, Contract DE-AC06-76RLO 1830 at PNNL, and grant# F265 to M. Dubey at Los Alamos National Laboratory (LANL).

User Facilities: Funding for data collection was provided by the Atmospheric Radiation Measurement (ARM) Program sponsored by the U.S. Department of Energy, Office of Biological and Environmental Research.

Research Area: Climate and Earth Systems Science

Research Team: Noopur Sharma and Swarup China, Michigan Technological University/PNNL; Janarjan Bhandari and Claudio Mazzoleni, Michigan Technological University; Kyle Gorkowski, Michigan Technological University/McGill University (Canada)/LANL; Manvendra Dubey, LANL; and Rahul A. Zaveri, PNNL

Reference: N. Sharma, S. China, J. Bhandari, K. Gorkowski, M. Dubey, R.A. Zaveri, and C. Mazzoleni, (2018). "Physical Properties of Aerosol Internally Mixed With Soot Particles in a Biogenically Dominated Environment in California." Geophysical Research Letters 45(20), 11,473-11,482. [DOI: 10.1029/2018GL079404].


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