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Sawdust reinvented into super sponge for oil spills

Environmentally friendly material tweaked to soak up to 5 times its weight in oil, float 4 months in icy, rough waters

December 12, 2016 Share This!

  • PNNL microbiologist George Bonheyo displays the original sawdust material (left) and how it appears after being chemically modified (right) to be exceptionally oil-attracting and buoyant, qualities that are ideal for cleaning up oil spills in the Arctic.

  • PNNL microbiologist Robert Jeters sprinkles PNNL's chemically modified sawdust onto a small oil spill inside the Arctic simulation lab, where researchers mimic extreme freezing conditions and make icy slush that is similar to what is found on the surface of the Arctic Sea.

  • PNNL is developing its modified sawdust oil spill response material so it can be used in controlled burns, a practice used during the 2010 Deepwater Horizon disaster that can significantly reduce the amount of oil in water and minimize its adverse environmental effects.

  • PNNL's modified sawdust material soaks up oil spilled on the surface of slushy water similar to what is found on the surface of the Arctic Sea.

  • Oil spreads on top of water with a slushy crust. The small ice chunks bob around and push oil below the surface, which makes cleaning up oil spills in the Arctic a challenge.

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SEQUIM, Wash. – Lowly sawdust, the sawmill waste that's sometimes tossed onto home garage floors to soak up oil spilled by amateur mechanics, could receive some new-found respect thanks to science.

Researchers at the Department of Energy's Pacific Northwest National Laboratory have chemically modified sawdust to make it exceptionally oil-attracting and buoyant, characteristics that are ideal for cleaning oil spills in the icy, turbulent waters of the Arctic. The nontoxic material absorbs up to five times its weight in oil and stays afloat for at least four months.

"Most of today's oil remediation materials are designed for warm water use," said PNNL microbiologist George Bonheyo, who leads the modified sawdust's development from PNNL's Marine Sciences Laboratory.

"But as ice retreats in the Arctic Sea, fossil fuel developers are looking north, and we need new oil spill response methods that perform well in extreme conditions," added Bonheyo, who also holds a joint appointment in bioengineering with Washington State University.

"The chance of an oil spill in the Arctic is real," said fellow PNNL microbiologist Robert Jeters, who is also part of the project. "We hope materials like our modified sawdust can help if an accident happens."

Fire & ice

Containing oil spills in cold waters is especially tricky, as bobbing ice chunks push oil below the water's surface, making it difficult to collect. The same goes for rough waters, whose tall, clashing waves disperse oil.

The modified saw dust pulls double duty. Beyond absorbing oil, it also enhances another approach to combatting oil spills — controlled burns. If changing weather or tides move spilled oil toward a sensitive area fast, oil can be burned before it can cause further harm. Called in-situ burning, the practice can significantly reduce the amount of oil in water and minimize its adverse environmental effects.

Bonheyo and his team looked to develop an environmentally friendly and inexpensive material that floats despite rough or freezing waters and can support in-situ burning. Not wanting to create more pollution if emergency responders can't retrieve oil cleanup material, Bonheyo's team considered other natural ingredients like rice hulls and silica. But they ultimately found their winner in a fine dust called wood flour. A woodworking byproduct, wood flour is often used to make wood composites.

To turn the dust into a thirsty oil mop, researchers chemically attach components of vegetable oil onto the material's surface. These attachments make the modified material oil-grabbing and water-shunning. The final product is a light, fluffy, bleached powder. The team is also trying out adding tiny, oil-eating microbes — fungi and bacteria — to the powder's surface so any left-behind material could naturally break down oil over time.

Just a sprinkle

Applying the modified sawdust is simple: sprinkle a thin layer over oil on the water's surface. The material immediately starts soaking up oil, creating a concentrated and solid slick that stays afloat thanks to the material's buoyant nature. The oil-soaked material can either be burned or retrieved.

The team is using PNNL's unique Arctic simulation lab in Sequim, Washington to evaluate the material in icy waters. The facility is a customized shipping container that cools down to as low as 5 degrees Fahrenheit, which prompts researchers to don snowmobile suits and ski masks while they work. Ice slush forms on the surface of water that circulates inside a 290-gallon raceway pond placed inside the bitterly cold lab space. Oil is spilled on the slushy surface, followed by a sprinkle of modified sawdust. Tests have shown the material's water-repellent nature prevents ice from forming on it, allowing it to soak up oil and remain at the surface.

Researchers are also testing how well the material performs in controlled burns. They conducted initial burns this fall at the U.S. Coast Guard and Naval Research Laboratory's Joint Maritime Test Facility near Mobile, Alabama. Burn tests continue today at PNNL's Marine Science Laboratory. Early results indicate a small amount of material enables burning of both thin and thick layers of spilled oil.

In the coming months, PNNL will further evaluate the modified sawdust. The material will need additional testing and approval by multiple agencies before it can be used at actual oil spills.

PNNL is developing the material for the Department of Interior's Bureau of Safety of Environmental Enforcement. BSEE is the lead federal agency charged with improving safety and ensuring environmental protection related to the offshore energy industry, primarily oil and natural gas on the U.S. Outer Continental Shelf.

The material's development team includes Bonheyo, Jeters, Yongsoon Shin, Jiyeon Park, Andrew Avila and Maren Symes.

Tags: Energy, Environment, Fundamental Science, Energy Production, Marine Research, Environmental Remediation, Chemistry, Microbiology, Materials

Interdisciplinary teams at Pacific Northwest National Laboratory address many of America's most pressing issues in energy, the environment and national security through advances in basic and applied science. Founded in 1965, PNNL employs 4,400 staff and has an annual budget of nearly $1 billion. It is managed by Battelle for the U.S. Department of Energy's Office of Science. As the single largest supporter of basic research in the physical sciences in the United States, the Office of Science is working to address some of the most pressing challenges of our time. For more information on PNNL, visit the PNNL News Center, or follow PNNL on Facebook, Google+, Instagram, LinkedIn and Twitter.

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